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Solid-Phase Synthesis of Oligosaccharides: Construction of a Dodecasaccharide
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1998
Year
New Solid-phase StrategyBioorganic ChemistrySolid-phase SynthesisBiochemistryDodecasaccharide 1Carbohydrate DonorsNatural SciencesEngineeringGlycobiologyNatural PolymerOrganic ChemistryPolysaccharideHemicelluloseCarbohydrate-protein InteractionBiomolecular EngineeringGlycosylation
Complicated oligosaccharides such as dodecasaccharide 1 can be constructed by a new solid-phase strategy. The attachment to the polymeric support (gray sphere) is through a photolabile linker (structure I), and thioglycosides serve as carbohydrate donors. Bn=benzyl, Bz=benzoyl.