Interaction of cationic monomer with sodium dodecyl sulfate in dilute aqueous solutions: ESR study

Abstract

The effect of a cationic monomer ( N,N,N,N -trimethyl[methacryloxyethyl]ammonium methyl sulfate) on the formation, structure, and local dynamics of associates resulted from the interaction of the monomer with sodium dodecyl sulfate in aqueous solutions was studied by ESR spectroscopy. In the presence of the monomer, micelles are formed at concentrations much lower than the CMC of the pure surfactant with the monomer molecules that form a condensed layer of counterions around a micelle of sodium dodecyl sulfate. The binding of surfactant micelles with the cationic monomer causes a significant decrease in the local molecular mobility of dodecyl sulfate ions.