[{[Pt(en)<sub>2</sub>][PtX<sub>2</sub>(en)<sub>2</sub>]}<sub>3</sub>][{(MX<sub>5</sub>)X<sub>3</sub>}<sub>2</sub>]⋅12 H<sub>2</sub>O: Quasi‐One‐Dimensional Halogen‐Bridged Pt<sup>II</sup>–Pt<sup>IV</sup> Mixed‐Valence Compounds with Magnetic Counteranions - Concepedia

Concepedia

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[{[Pt(en)<sub>2</sub>][PtX<sub>2</sub>(en)<sub>2</sub>]}<sub>3</sub>][{(MX<sub>5</sub>)X<sub>3</sub>}<sub>2</sub>]⋅12 H<sub>2</sub>O: Quasi‐One‐Dimensional Halogen‐Bridged Pt<sup>II</sup>–Pt<sup>IV</sup> Mixed‐Valence Compounds with Magnetic Counteranions

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Citations

11

References

2004

Year

Masahiro Yamashita, Daisuke Kawakami, Satoshi Matsunaga, Yoshio Nakayama, Mari Sasaki, Shinya Takaishi, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken‐ichi Sugiura, Yoshiki Wada,

Angewandte Chemie International Edition

EngineeringLow-dimensional MagnetismChemistryWater MoleculesInorganic MaterialQuantum MaterialsMaterials ScienceInorganic ChemistryAttractive ComplexesMagnetic CounteranionsPhysical ChemistryQuantum ChemistryCrystallographyInorganic SynthesisNatural SciencesCoordination ComplexMolecular ComplexMain Group ChemistryFunctional Materials

Abstract

Attractive complexes: Hexagonal micropores similar to zeolites have been observed in mixed-valence PtII–PtIV compounds with magnetic counteranions (see X-ray crystal structure). The micropores contain 12 water molecules per molecular unit which can be desorbed by heating the complexes to 100 °C and re-adsorbed by cooling to 20 °C without affecting the skeletal structure.

References

	Year	Citations

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