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Structure and photochemistry of new base-stabilized silylene (silanediyl) complexes R2(HMPA)Si:M(CO)n of iron, chromium, and tungsten (R = tert-BuO, tert-BuS, MesO, 1-AdaO, 2-AdaO, NeopO, TritO, Me, Cl; M = Fe, n = 4; M = Cr, W, n = 5): sila-Wittig reaction of the base-free reactive intermediate [Me2Si:Cr(CO)5] with dimethyl carbonate
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Materials ScienceInorganic ChemistryEngineeringPhotochemistryCoordination ComplexAltmetric Attention ScoreComplexes R2New Base-stabilized SilyleneMolecular ComplexDimethyl CarbonateChemistryInorganic SynthesisInorganic Compound
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and photochemistry of new base-stabilized silylene (silanediyl) complexes R2(HMPA)Si:M(CO)n of iron, chromium, and tungsten (R = tert-BuO, tert-BuS, MesO, 1-AdaO, 2-AdaO, NeopO, TritO, Me, Cl; M = Fe, n = 4; M = Cr, W, n = 5): sila-Wittig reaction of the base-free reactive intermediate [Me2Si:Cr(CO)5] with dimethyl carbonateChristian Leis, Dallas L. Wilkinson, Hermann Handwerker, Christian Zybill, and Gerhard MuellerCite this: Organometallics 1992, 11, 2, 514–529Publication Date (Print):February 1, 1992Publication History Published online1 May 2002Published inissue 1 February 1992https://pubs.acs.org/doi/10.1021/om00038a004https://doi.org/10.1021/om00038a004research-articleACS PublicationsRequest reuse permissionsArticle Views425Altmetric-Citations73LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts