Journal of Applied Polymer Science · 1979 · 34 citations · 0 references
EngineeringMaterials SciencePhysicsFluid DynamicsFluid MechanicsRheologyFlow BehaviorNon-newtonian Fluid FlowPolymer RheologyRheology Of Complex FluidsViscous FlowAnomalous Flow BehaviorPolymer Solution Flow BehaviorPolymer Solution RheologyPolymeric Fluid DynamicsRheology Of Polymer SolutionsRheometryShear StressSteady Flow
Flow irregularities have been visually observed in solutions of polyacrylamide of high molecular weight on shear in a cone-and-plate rheometry (gap angle 2.3°). This anomalous flow was found to depend on molecular weight, concentration, and solvent. The onset of flow irregularities were generally at shear rates < 5 sec−1. A dimensional analysis shows that the elastic component of the fluid is responsible for the anomalous flow. The onset of flow irregularities has been predicted from measurements of recoverable strain as a function of shear stress.