Concepedia

A Concise Approach to the Synthesis of <i>opp</i>-Dibenzoporphyrins through the Heck Reaction

Rohit Deshpande, Lin Jiang, Grégory Schmidt, John Rakovan, Xiaoping Wang, Kraig A. Wheeler, Hong Wang

Organic Letters · 2009 · 78 citations · 32 references

DOI

Concepts

Abstract

A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-pi electrocyclization, and subsequent aromatization occur in one pot.

References

32

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Carsten Borek, Kenneth Hanson, Peter I. Djurovich et al. · Angewandte Chemie International Edition · 2007 · 271 citations · Full text

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A new synthesis of benzoporphyrins using 4,7-dihydro-4,7-ethano-2H-isoindole as a synthon of isoindole

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Quinoxaline-Fused Porphyrins for Dye-Sensitized Solar Cells

Seunghun Eu, Shinya Hayashi, Tomokazu Umeyama et al. · The Journal of Physical Chemistry C · 2008 · 171 citations

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Novel Versatile Synthesis of Substituted Tetrabenzoporphyrins

Olga S. Finikova, Andrei V. Cheprakov, I. P. Beletskaya et al. · The Journal of Organic Chemistry · 2003 · 161 citations

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.beta.-Halogenated-pyrrole porphyrins. Molecular structures of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin, nickel(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin, and nickel(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin

Dominique Mandon, P. Ochenbein, J. FISCHER et al. · Inorganic Chemistry · 1992 · 153 citations

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