Concepedia

Stereoselective Synthesis of α-Alkyl-β-keto Imides via Asymmetric Redox C−C Bond Formation between α-Alkyl-α-diazocarbonyl Compounds and Aldehydes

Takuya Hashimoto, Hisashi Miyamoto, Yuki Naganawa, Keiji Maruoka

Journal of the American Chemical Society · 2009 · 75 citations · 30 references

DOI

Concepts

Abstract

Asymmetric redox C-C bond formation between alpha-alkyl-alpha-diazocarbonyl compounds and aldehydes was developed as a practical and general method for the construction of alpha-alkyl-beta-keto imides having a chiral nonracemic tertiary stereogenic center.

References

30

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