MASS TRANSPORT PROPERTIES OF A FLOW-THROUGH ELECTROLYTIC REACTOR USING A POROUS ELECTRODE: PERFORMANCE AND FIGURES OF MERIT FOR Pb(II) REMOVAL

Abstract

The removal of lead from an acid borate-nitrate solution containing Pb(II) was used to characterize the mass transport properties of an electrolytic reactor with reticulated vitreous carbon cathodes, operated in the flow-through mode. Current potential curves recorded at a rotating vitreous carbon disc electrode were used to determine the diffusion coefficient for Pb(II) under the conditions of the experiments. The performance and figures of merit of the electrolytic reactor were investigated by using different flowrates and cathode porosities. Dimensionless Sherwood and Reynolds numbers were correlated to characterize the mass transport properties of the reactor, and they were fitted to the equation Sh=24Re0.32Sc0.33.