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Electrochemical generation and reactivity of organo-cobalt(IV) and -rhodium(IV) chelates
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1975
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Inorganic ChemistryChemical EngineeringCarbonium IonEngineeringMolecular ElectrochemistryCoordination ComplexElectrochemical GenerationElectrosynthesisσ-Bonded Organic LigandStable SpeciesOrganometallic ElectrochemistryCatalysisRedox ChemistryChemistryElectrode Reaction MechanismElectrochemistryInorganic Compound
Electro-oxidation of organo-cobalt(III) and -rhodium(III) chelates yields fairly stable species retaining a σ-bonded organic ligand, which behaves as a carbonium ion being readily transferred to nucleophiles.