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Palladium-Catalyzed Intramolecular Asymmetric Hydroamination of Alkynes
245
Citations
15
References
2004
Year
Cross-coupling ReactionEngineeringInternal AlkynesChiral Phosphine LigandOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHigh EeAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
The Pd-catalyzed reaction of internal alkynes with tethered amino groups in the presence of PhCO2H and RENORPHOS as chiral phosphine ligand is reported. Various five- and six-membered nitrogen-containing heterocycles were obtained in good to high yield with moderate to high ee.
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