A Stable Hybrid Bisphosphonate Polyoxometalate Single‐Molecule Magnet

Hani El Moll, Anne Dolbecq, Jérôme Marrot, Guillaume Rousseau, Mohamed Haouas, Françis Taulelle, Guillaume Rogez, Wolfgang Wernsdorfer, Bineta Keita, Pierre Mialane

Chemistry - A European Journal · 2012 · 79 citations · 37 references

Concepts

Abstract

A new functionalizable polyoxometalate platform: The heptanuclear CoII polyoxometalate complex [{(B-α- PW9O34)Co3(OH)(H2O)2(O3PC(O)- (C3H6NH3)PO3)}2Co]14− represents a unique example of a magnetic, stable, functionalizable polyoxotungstate platform, and behaves as a single-molecule magnet (see figure).

References

37