Concepedia

Abstract

Seven methods (Voigt model, Maxwell model, operator equation, mechanical impedance function, creep curve, relaxation curve, and dynamic modulus function) of specifying viscoelastic behavior are discussed. A number of exact relations between these methods of specification are worked out in detail. The majority of these relations are simple enough to be of practical value although a few are too cumbersome. Approximate relationships between the creep curve, the relaxation curve, Maxwell model, and Voigt model are discussed; and numerical examples show the magnitude of errors introduced by the approximation to be small even in quite unfavorable cases. A consideration of the practical utility and physical meaning of the various methods of specification distinguishes between (1) those of general descriptive value and those of direct experimental value; (2) those useful in a phenomenological study of mechanical behavior and those more suited to a formulation of molecular theory. A summary of the present molecular theories is presented together with their interpretation in terms of the Voigt and Maxwell specifications.

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