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Chemical trend of Ln–M exchange couplings in heterometallic complexes with Ln = Gd, Tb, Dy, Ho, Er and M = Cu, V
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Citations
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References
2010
Year
Magnetic PropertiesEngineeringLow-dimensional MagnetismChemical TrendTheoretical Inorganic ChemistryMagnetic ResonanceChemistryMagnetic MaterialsMagnetismDouble μ-Oxo-bridgesMaterials ScienceInorganic ChemistryFerromagnetic JLn–m Exchange CouplingsPhysics4F-3d Exchange CouplingsFerromagnetismNatural SciencesCoordination ComplexMolecular ComplexHeterometallic Complexes
The 4f-3d exchange couplings were definitively and precisely determined in the dinuclear complexes (Ln-M) involving double μ-oxo-bridges, by means of combined high-frequency electron paramagnetic resonance and pulsed-field magnetization techniques, revealing a monotonic decrease of ferromagnetic J(Ln-Cu) in the order of the atomic number, (64)Gd to (68)Er.
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