Organic Letters · 2006 · 133 citations · 6 references
Natural SciencesChemistryCatalysisInorganic ChemistryOrganometallic ChemistryHeterocycle SynthesisHeterocyclic ChemistryInorganic SynthesisMetal CatalysisOrganometallic SynthesisManganese ChelationManganese ChemistryMild Reaction ConditionsRegioselectivityThiazole ChemistryThiazole Synthesis
[Structure: see text] A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)(3).2H2O under mild conditions give phosphonated products in high yield and good regioselectivity.
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Palladium-catalyzed phosphination of functionalized aryl triflates
Fuk Yee Kwong, Chi Wai Lai, Michael Yu et al. · Tetrahedron · 2003 · 54 citations