Chemistry of Materials · 1997 · 362 citations · 12 references
Natural SciencesChemistryMaterials ScienceColloid ScienceNanomaterialsPhysical ChemistryEmulsion FormationInorganic NanoparticlesNanoparticle SurfacesNanoporous MaterialsPorous MaterialsSurfactantsAbsorption StudiesCationic SurfactantsIonic SurfactantsMesoporous MaterialsMesoporous NanomaterialsPorous SilicaPorous Silica MaterialsSurface Area
Large, hard, transparent, mesoporous silica spheres are synthesized in one step by using oil-in-water emulsion chemistry under basic conditions with cationic surfactants and (n-BuO)4Si. The pores are shown by TEM and nitrogen absorption studies to be monodispersed in size, with total surface area over 1000 m2/g.
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Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
Charles T. Kresge, M. E. Leonowicz, Wiesław J. Roth et al. · Nature · 1992 · 16.1K citations
Oil-Water Interface Templating of Mesoporous Macroscale Structures
Stefan Schacht, Quan Huo, I. G. Voigt‐Martin et al. · Science · 1996 · 795 citations