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Silylenenickel(0) or Silyl(silylene)platinum(II) Complexes by Reaction of Si[(NCH<sub>2</sub>Bu<sup>t</sup>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>-1,2] with [NiCl<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>], [Ni(cod)<sub>2</sub>], or [PtCl<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>]
136
Citations
16
References
1998
Year
Inorganic ChemistryChemical EngineeringEngineeringBiochemistryNatural SciencesCoordination ComplexNeutral LigandCrystalline Diamagnetic ComplexAnionic LigandMolecular ComplexCatalysisChemistryInorganic SynthesisInorganic Compound
The stable silylene Si[(NCH2But)2C6H4-1,2] [abbreviated as (1) (4 equiv) with 1 equiv each of [NiCl2(PPh3)2], [Ni(cod)2], or [PtCl2(PPh3)2] in benzene affords the crystalline diamagnetic complex (2), (3), or (4), while from 1 (5 equiv) and [NiCl2(PPh3)2] the product was 3. The diversity of behavior of 1, functioning as (i) a neutral ligand, (ii) a reducing agent, and/or (iii) a source of the anionic ligand is noteworthy.
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