Co 2 + Ti 4 + substituted Z-type barium ferrite with enhanced imaginary permeability and resonance frequency

Abstract

Co 2 + Ti 4 + substitution for Fe3+ in Co2Z (Ba3Co2Fe24O41) has been prepared. The crystal structure and static and high-frequency magnetic properties have been studied for Ba3Co2+xTixFe24−2xO41 and the corresponding ferrite/polymer composites. As compared to the general Co2Z ferrite/polymer composite, the CoTi substituted ferrite/polymer composite with x=1.0 has a high natural resonance frequency (4.5GHz), due to its large out-of-plane anisotropy fields Hθ. Furthermore, the maximum imaginary permeability μmax″ is increased by about 50%. The increase is attributed to a decreased damping coefficient, based on the curve-fitted results to the complex permeability spectra. The composites are good electromagnetic attenuation materials with low reflectivity and broad bandwidth at microwave frequencies.