Journal of Chemical & Engineering Data · 2002 · 23 citations · 9 references
Natural SciencesChemical EngineeringChemistryComputational ChemistryMultiphase FlowPhysical ChemistryLiquid-liquid InterfacesPhase DiagramsPhase EquilibriaPhase EquilibriumThermodynamics Of Phase EquilibriaThree-phase FlowAtmospheric PressureComposition-dependent Interaction ParametersInteraction ParametersLiquid - Liquid EquilibriumLiquid-liquid EquilibriaLiquid-liquid EquilibriumLiquid-vapor EquilibriaTernary Phase Equilibria
Liquid−liquid equilibria of the ternary system water + dodecane + 2-butyloxyethanol in the temperature range from 25.0 °C to 65.0 °C were performed at atmospheric pressure. The experimental data were correlated with the UNIQUAC model and good agreement was obtained. For the system with a three-liquid-phase-coexisting region, all six UNIQUAC interaction parameters can be numerically regressed by simply minimizing the deviation of the compositions of three coexisting liquid phases.
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