Angewandte Chemie International Edition · 2005 · 107 citations · 70 references
Natural SciencesChemistryMaterials ScienceCatalysisInorganic ChemistryOrganic ChemistryCoordination ChemistryCoordination PolymersCucurbituril ChemistryMetal-ligand BondingSupramolecular MaterialsTransition Metal ComplexesComplexation ChemistryCucurbituril-based MaterialsHelical AssemblyIntermolecular Metal-ligand InteractionsMetal CoordinationMetal-ligand Coordination PolymersMetal-organic Supramolecular AssembliesSupramolecular Coordination Polymers
An anion-exchange strategy was used to prepare two helical structures made up of cucurbituril and asymmetric copper(II) complexes containing 8-hydroxyquinoline-5-sulfonate and 3,5-diiodosalicylate (right half of picture) or 3-iodobenzoate (left half). The shape-matching interactions between cucurbituril and the copper complexes were assisted by the iodo substituents.
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Comprehensive supramolecular chemistry
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