Concepedia

A Simple Route from Glucal to Cerny Epoxides

Gilbert Lauer, Franz Oberdorfer

Angewandte Chemie International Edition in English · 1993 · 24 citations · 12 references

DOI

Concepts

Abstract

Previously difficult to obtain, dianhydropyranoses 1 and 2 can now be synthesized from the pseudoglucal derivative 3 in one step with surprising ease and in good yields. The bridged glucoside 3 is prepared from glucal by an intramolecular ring-closure novel for this type of compound. R  H.

References

12

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Frederick Sweet, R. K. Brown · Canadian Journal of Chemistry · 1968 · 45 citations

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Syntheses of 3-deoxy-3-substituted-<scp>D</scp>-glucose derivatives. Part I. Improvements in preparation of and nucleophilic additions to 1,6:2,3-dianhydro-4-<i>O</i>-benzyl-β-<scp>D</scp>-allopyranose

T. Bruce Grindley, Gerry J. Reimer, Jaroslav A. Kralovec et al. · Canadian Journal of Chemistry · 1987 · 30 citations · Full text

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