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Synthesis of 4,5-Ethylenedithio-4′,5′-(2-oxatrimethylenedithio)tetrathiafulvalene (EOTT) and Electrical Conductivities of Their Ion-Radical Salts
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Citations
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References
1990
Year
Materials ScienceInorganic ChemistrySeveral Ion-radical SaltsEngineeringOrganic ElectrochemistryMolecular ElectrochemistryElectrosynthesisMolecule-based MaterialOrganometallic ElectrochemistryElectrochemical CrystallizationOrganic ChemistryMolecular MaterialSynthetic ChemistryChemistryTheir Ion-radical SaltsMetallic BehaviorElectrical Conductivities
Abstract The title molecule (EOTT), which is a new unsymmetrical TTF derivative, was synthesized, and several ion-radical salts of EOTT were prepared by electrochemical crystallization. Room temperature conductivities of these salts were found to be in the range of 10−1–102 S cm−1. Among them, EOTT2IBr2 and EOTT2AuI2 showed metallic behavior in electrical conduction down to ca. 15 and 4.2 K, respectively.
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