Photoelectrical properties, energy level spectra, and photogeneration mechanisms of pentacene

Abstract

The main optical, dark and photoconductivity, photo-emf, and photoemission characteristics are studied for thin-layers of pentacene (Pc) crystals. It is shown that in the h = = 2.2 to 4.0 eV spectral region intrinsic photogeneration is dominant in Pc crystals, presumably proceeding via an autoionization mechanisms with a threshold value Ec = = (2.20 ± 0.05) eV. Whereas in the hvv = 1.4 to 2.2 eV spectral region an exciton photogeneration mechanism, namely, generation of excess charge carriers through triplet exciton-trapped hole interaction, seems most probably. The energy level spectra of neutral and ionized states of the Pc crystal are determined. The Pc crystal ionization energy Ic equals to (5.07 ± 0.05) eV; the forbidden energy gap ΔE0 = (2.20 ± 0.05) eV; the intrinsic dark conductivity activation energy E = ΔE0/2 = (1.15 ± 0.15) eV. The electron affinity Ac of the Pc crystal, determined by three independent methods equals to (2.87 ± 0.10) eV, (2.70 ± 0.15) eV, or (2.73 ± 0.2) eV, respectively. The characteristic energies of the quasi-continuous trap distribution for vacuum evaporated thin Pc crystals layers are kTc = 0.12 eV in an exponential approximation and ± = 0.28 eV in a Gaussian one as determined from SCLC measurements. [Russian Text Ignored].