Magnetic and optical studies of spin and charge ordering in (TMTTF)₂AsF₆

Abstract

We studied the magnetic and electronic properties of the insulating charge-transfer salt (TMTTF) 2 AsF 6 by electron spin resonance (ESR), SQUID magnetometer and optical conductivity measurements. For the first time, the lattice dynamics was investigated in the vicinity of the charge order transition. We found a splitting of the electron-molecular-vibration coupled totally symmetric intramolecular a g (v 3 ) mode below the charge-order transition at 100 K. From this result a charge disproportionation on the TMTTF molecular stacks of about 2:1 can be estimated. The spin degrees of freedom were investigated by ESR and SQUID. At high temperatures (TMTTF)2AsF6 behaves like a antiferromagnetic S=1/2 Heisenberg chain. Below 13 K, we observed an exponential decrease of the spin susceptibility indicating the phase transition into the spin-Peierls ground state.