Journal of the American Chemical Society · 2006 · 120 citations · 5 references
Natural SciencesChemistryMaterials ScienceElectrochemistryElectronic MaterialsEnergy MaterialsElectrochemical CellsElectrochemical Energy ConversionPhotoelectrochemical MaterialsPhotoelectrochemistryRedox-active MaterialsSolar CellsDye-sensitized Solar CellsElectrochemical Electron TransferElectrolyte ChemistryElectrolyte CompositionElectron-transfer MaterialsOrganic Redox MaterialsPhotoelectrochemical CellsRedox-mediated Systems
The electrochemical and photoelectrochemical study of noncorrosive electron-transfer mediator mixtures for DSC is reported. These mixtures, characterized by the presence of kinetically fast organic or metal-organic redox couples in conjunction with a Co(II)/(III) relay, exhibited maximum photon-to-current conversion efficiencies (IPCE %) exceeding 80% when employed in the presence of a suitably designed MLCT sensitizer, rivaling with the performances of the classical I-/I3- electrolyte.
5
Hervé Nusbaumer, Jacques‐E. Moser, Shaik M. Zakeeruddin et al. · The Journal of Physical Chemistry B · 2001 · 416 citations · Full text