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The selective conversion of n-pentane into pent-1-ene via trihydrido(trans-penta-1,3-diene)bis(triarylphosphine)rhenium
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1982
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Inorganic ChemistryEngineeringHeterocyclicOrganic ChemistryOrganometallic CatalysisChemistryHigh SelectivityPharmacologyDerivative (Chemistry)Enantioselective SynthesisSelective Conversion
Treatment of n-pentane with heptahydridobis(triarylphosphine)rhenium and 3,3-dimethylbutene gives trihydrido(trans-penta-1,3-diene)bis(triarylphosphine)rhenium; trimethyl phosphite converts this, with high selectivity, into pent-1-ene.