Coherent acoustic oscillations in metallic nanoparticles generated with femtosecond optical pulses

Abstract

Nonthermal generation of coherent-acoustic phonons is observed in metallic nanoparticles of tin and gallium, which are solid and liquid, respectively, at room temperature, by applying femtosecond pump-and-probe spectroscopy. Oscillations in the photo-induced differential reflection are clearly detected in the picosecond time domain. The measured period increases approximately linearly with size over a wide range and extracted sound velocities are consistent with those of bulk. Transition to ballistic regime in carrier excitation is also discussed on the basis of the disappearance of oscillations for particle sizes below hot-carrier mean free paths.