Publication | Closed Access
Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW<sub>10</sub>O<sub>36</sub>]<sup>8−</sup>: A Totally Inorganic Oxygen-Evolving Catalyst
587
Citations
20
References
2008
Year
Materials ScienceInorganic ChemistryOxygen Reduction ReactionEngineeringBiochemistryNatural SciencesTemplate-directed MetalationHeterogeneous CatalysisPolyoxometalate EmbeddingRu4o6 FragmentSolution EvidenceOrganometallic CatalysisCatalysisRedox ChemistryChemistryCatalyst PreparationInorganic SynthesisSolid State
Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.
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