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Calix[4]arene-Capped Tetraphenylporphyrin. Synthetic Approach to a Chiral Capped Porphyrin with Regular C4 Symmetry
32
Citations
4
References
1994
Year
Regular C4 SymmetryEngineeringC4 Symmetry CharacteristicSynthetic ApproachOrganic ChemistryUnique Guest-binding PropertiesChiral PillarsChemistrySupramolecular ChemistryChiral Capped PorphyrinBiophysicsBiomolecular EngineeringHost-guest Chemistry
Abstract A tetraphenylporphyrin capped with a calix[4]arene through four chiral pillars has been synthesized. This molecule retains C4 symmetry characteristic of porphyrins. The preliminary experiments indicated that the cavity shows unique guest-binding properties.
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