Concepedia

The reaction of 1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane with cytosine arabinoside and 1-(6-deoxy-α-L-talofuranosyl)uracil

Wojciech T. Markiewicz, N. Sh. Padyukova, Z. Samek, J. Smrt

Collection of Czechoslovak Chemical Communications · 1980 · 39 citations · 0 references

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Abstract

1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane ( I ) reacts with cytosine arabinoside ( II ) in pyridine under the formation of 3',5'-O-(tetraisopropyldisiloxane-1,3-diyl)cytosine arabinoside ( IIIa ) and with 1-(6'-deoxy-α-L-talofuranosyl)uracil ( V ) under the formation of 2',3'-O-(tetraisopropyldisiloxane-1,3-diyl) 1-(6-deoxy-α-L-talofuranosyl)uracil ( VIa ).