Concepedia

A Thallium Mediated Route to σ-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I)

B.J. Liddle, Sergey V. Lindeman, Daniel L. Reger, J.R. Gardinier

Inorganic Chemistry · 2007 · 25 citations · 14 references

DOIFull text

Open access

Concepts

Abstract

A simple, one-pot preparation of rhenium(I) sigma-arylalkynyl complexes is reported using thallium(I) hexafluorophosphate as a halogen abstraction agent. This new route to rhenium sigma-alkynyls enjoys higher yields compared to analogous preparations using silver salts by eliminating potential electrochemical degradation pathways.

References

14

Ground and excited state electron transfer processes involving fac-tricarbonylchloro(1,10-phenanthroline)rhenium(I). Electrogenerated chemiluminescence and electron transfer quenching of the lowest excited state

John C. Luong, Louis Nadjo, Mark S. Wrighton · Journal of the American Chemical Society · 1978 · 183 citations

, , +15

Substituent constant correlations as predictors of spectroscopic, electrochemical, and photophysical properties in ring-substituted 2,2'-bipyridine complexes of rhenium(I)

Janel K. Hino, Leopoldo Della Ciana, Walter J. Dressick et al. · Inorganic Chemistry · 1992 · 132 citations

, , +14

Luminescent carbon-rich rhenium(i) complexes

Vivian Wing‐Wah Yam · Chemical Communications · 2001 · 130 citations

, , +12

Synthesis and Photophysics of Luminescent Rhenium(I) Acetylides-Precursors for Organometallic Rigid-Rod Materials. X-ray Crystal Structures of [Re(tBu2bpy)(CO)3(tBuC.tplbond.C)] and [Re(tBu2bpy)(CO)3Cl]

Vivian Wing‐Wah Yam, Victor Chor-Yue Lau, Kung‐Kai Cheung · Organometallics · 1995 · 103 citations

, , +9

Synthesis, Photophysical Properties, and Photoinduced Luminescence Switching of Trinuclear Diimine Rhenium(I) Tricarbonyl Complexes Linked by an Isomerizable Stilbene-like Ligand

Shih‐Sheng Sun, Alistair J. Lees · Organometallics · 2001 · 99 citations

, , +15