Synthesis of New Bicyclic P−N Ligands and Their Application in Asymmetric Pd-Catalyzed π-Allyl Alkylation and Heck Reaction

Abstract

[structure: see text] The synthesis of phosphine oxazoline ligands based on P-chiral 1-phosphanorbornadienes is reported. The use of these ligands in palladium catalyzed asymmetric allylation and Heck reaction is described.