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Highly Active Copolymerization of Ethylene and Dicyclopentadiene with [(η1-<i>t</i>-BuN)SiMe2(η1-C29H36)]TiMe2(THF) Complex
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Citations
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References
2008
Year
EngineeringOrganic ChemistryChemistryActive CopolymerizationPolymersChemical EngineeringMacromolecular EngineeringOrganometallic CatalysisPolymer ChemistryMaterials ScienceEthylene–dicyclopentadiene CopolymerizationRemarkable Catalytic ActivityHigh Glass-transition TemperatureCatalysisOrganometallic PolymerBiomolecular EngineeringMolecular ComplexCoordination PolymerPolymer ReactionPolymer Synthesis
Abstract A new ansa-fluorenylamidodimethyltitanium complex 1 was synthesized and applied for ethylene–dicyclopentadiene copolymerization using modified methylaluminoxane (MMAO) as a cocatalyst at 50 °C. 1–MMAO exhibited the remarkable catalytic activity for the copolymerization and gave a copolymer with high glass-transition temperature of 191 °C.
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