Negative Thermal Quenching Behavior and Long Luminescence Lifetime of Surface-State Related Green Emission in ZnO Nanorods

Haiping He, Zhizhen Ye, Shisheng Lin, Binghui Zhao, Jingyun Huang, Haiping Tang

The Journal of Physical Chemistry C · 2008 · 52 citations · 27 references

Concepts

Abstract

An experimental study of the luminescence intensity and time decay of the green band (GB) in ZnO nanorods as a function of temperature is reported. The GB intensity shows a negative thermal quenching behavior in the temperature range of 100−200 K. The increase of intensity is accompanied by a remarkable increase of lifetime with a maximum of ∼1.7 ms at 150 K, which is much longer than those documented values. We suggest that a multiple trapping−detrapping mechanism is responsible for the long lifetime. The results indicate that the surface state greatly influences the dynamics of the GB in ZnO nanostructures.

References

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