Concepedia

Polynitrile-bridged two-dimensional crystal: Eu(iii) complex with strong fluorescence emission and NLO property

Jing-Min Shi, Wen Xu, Qingyun Liu, Fengling Liu, Zhen‐Li Huang, Hong Lei, Wen‐Tao Yu, Qi Fang

Chemical Communications · 2002 · 72 citations · 5 references

DOI

Concepts

Abstract

The first polynitrile coordinated lanthanide complex ([Eu(cda)3(H2O)3].H2O) infinity (cda = carbamyldicyanomethanide anion) has been synthesized and the two-dimensional structure coordination polymer exhibits strong fluorescence emission and strong powder second harmonic generation efficiency (16.8 times that of urea).

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