Publication | Closed Access
Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation
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Citations
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References
2008
Year
HeterocyclicBiochemistryBiphep-rh Asymmetric HydrogenationSole SourceSitu ResolutionNatural SciencesOrganic ChemistryPure BicycloStereoselective SynthesisChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisDiphosphine BiphepAsymmetric Hydrogenation
In situ resolution of the rapidly racemising diphosphine BIPHEP and its relatives with the cationic Rh complex of (S,S)-bicyclonona-2,6-diene permits the asymmetric hydrogenation of dehydroamino esters.
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