Publication | Open Access
Amphiphilic Carbohydrate-Based Mesogens, 2 [1] Aldose Di-n-alkyl Dithioacetals: Novel Double-Tailed Thermotropic Liquid Crystals
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1987
Year
Bioorganic ChemistryEngineeringGlycobiologyMolecular BiologyOrganic ChemistryPolysaccharideCarbohydrate-protein InteractionChemistryChemical BiologyEnzymatic ModificationBiosynthesisStereoselective SynthesisCrystal FormationGlycosylationAmphiphilic Carbohydrate-based MesogensBiochemistryN-alkyl ThiolsEnantioselective SynthesisBiomolecular EngineeringNatural SciencesMetabolismSynthetic Chemistry
Mercaptolyses of the pentoses [D-lyxose (1), D-xylose (2), L-arabinose (3)] and hexoses [D-mannose (4), D-glucose (5), D-galactose (6)] with n-alkyl thiols having chain lengths ≥ C 6 gives mesogenic aldose di-n-alkyl dithioacetals 7-12.