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Unprecedented reaction of a thiocarbonyl ylide with carbonyl compounds: a novel synthesis of 1,3-oxathiolanes
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1987
Year
Corresponding 1,3-OxathiolanesCarbonyl CompoundsEngineeringBiochemistryNatural SciencesThioformylium MethylideFluoride IonOrganic ChemistryThiocarbonyl YlideNovel SynthesisChemistryNatural Product SynthesisChemical DerivativeSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Thioformylium methylide, readily generated from chloromethyl trimethylsilylmethyl sulphide with the aid of fluoride ion, reacts with carbonyl compounds such as aldehydes, α-diketones, and α-oxo amides to give the corresponding 1,3-oxathiolanes in good yields.