Publication | Closed Access
A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation
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Citations
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References
2011
Year
Materials ScienceInorganic ChemistryChemical EngineeringLewis Base SitesEngineering1-Hexene/n-hexane SeparationSupramolecular AssemblySelf-assemblyInorganic PolymerPost-synthetic FunctionalizationCoordination PolymerChemistryMetal-organic PolyhedronUnique 3-Dimensional SurfaceHybrid MaterialsFunctional MaterialsPolymer ChemistryPost-synthetic Modification
PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.
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