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The synthesis and properties of dimethylgallane: structure of the dimer Me<sub>2</sub>Ga(µ-H)<sub>2</sub>GaMe<sub>2</sub>in the gas phase as determined by electron diffraction
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1986
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Inorganic ChemistryChemical EngineeringEngineeringGas PhaseNatural SciencesOrganic ChemistryPredominant Vapour SpeciesElectron DiffractionSynthetic ChemistryMain Group ChemistryQuantum ChemistryChemistryMolecular ChemistryChemical PropertiesDimer Me2gaInorganic SynthesisInorganic Compound
Dimethylgallane, best synthesised by the reaction between trimethylgallane and sodium tetrahydrogallate, has been characterised by its spectroscopic and chemical properties; electron diffraction has established the structure of the dimer Me2Ga(µ-H)2GaMe2, the predominant vapour species at low pressure.