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An Example of the Co-Occurrence of Enantiomeric Labdane-Type Diterpenes in the Leaves of Mimosa hostilis.
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1999
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Bioorganic ChemistryBotanyLabdane-type Diterpenes 4Medicinal FungiPharmaceutical ChemistryMedicinal ChemistryX-ray Crystallographic AnalysisMimosa HostilisPhytochemicalBiochemistryAbsolute ConfigurationsPharmacologyBiologyNatural SciencesEnantiomeric Labdane-type DiterpenesSymbiosisPhytochemistryMedicineDrug Discovery
Two labdane-type diterpenes 4 and 5 isolated from the Brazilian medicinal plant Mimosa hostilis were confirmed to have absolute configurations in enantiomeric relation to each other by X-ray crystallographic analysis of p-bromophenyl carbamate derivative 5a and comparison between 4a and 5b, readily available from 5a.