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Some metal complexes of macrocyclic ligands incorporating the 1,10-phenanthroline group. X-Ray crystal structure of the manganese(II) complex
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1978
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Inorganic ChemistryEngineeringBiochemistryX-ray StructureNatural SciencesCoordination ComplexOrganic ChemistryMacrocyclic LigandsX-ray Crystal StructureMetal ComplexesChemistryMetal Macrocyclic SystemsMolecular ComplexCrystallographyInorganic SynthesisBiophysics1,10-Phenanthroline GroupInorganic Compound
The incorporation of 1,10-phenanthroline into metal macrocyclic systems is reported; the presence of π-delocalisation in these systems is considered and the X-ray structure of a six co-ordinate pentagonal pyramidal MnII complex incorporating the 1,10-phenanthroline group is consistent with this view.