Concepedia

Ligand-Free Ag(I)-Catalyzed Carboxylation of Terminal Alkynes with CO<sub>2</sub>

Xiǎo Zhang, Wen‐Zhen Zhang, Xiang Ren, Lin-Lin Zhang, Xiao‐Bing Lu

Organic Letters · 2011 · 199 citations · 74 references

DOI

Concepts

Abstract

A convenient approach to selectively prepare a wide range of functionalized propiolic acids was developed by AgI-catalyzed carboxylation of terminal alkynes using carbon dioxide as carboxylative agent under ligand-free conditions.

References

74

Utilisation of CO2 as a chemical feedstock: opportunities and challenges

Michele Aresta, Angela Dibenedetto · Dalton Transactions · 2007 · 1.4K citations

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Conversion of Carbon Dioxide into Methanol with Silanes over N‐Heterocyclic Carbene Catalysts

Siti Nurhanna Riduan, Yugen Zhang, Jackie Y. Ying · Angewandte Chemie International Edition · 2009 · 593 citations · Full text

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Recent developments in carbon dioxide utilization under mild conditions

Siti Nurhanna Riduan, Yugen Zhang · Dalton Transactions · 2010 · 579 citations

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Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

Andreas Berkefeld, Warren E. Piers, Masood Parvez · Journal of the American Chemical Society · 2010 · 504 citations

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Carboxylation of C−H Bonds Using <i>N</i>-Heterocyclic Carbene Gold(I) Complexes

Inẽ I. F. Boogaerts, Steven P. Nolan · Journal of the American Chemical Society · 2010 · 501 citations

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