Physical Review · 1964 · 164 citations · 26 references
Two-photon IonizationEngineeringChemistryOptical PropertiesUltracold AtomNonrelativistic Dipole ApproximationIon EmissionQuantum SciencePhotonicsPhysicsRelativistic Laser-matter InteractionAtomic PhysicsHydrogenQuantum ChemistryGeneral TheoryPhoton StatisticExcited State PropertyQuantum OpticNatural SciencesSpectroscopyApplied Physics
This paper discusses the general theory of two-photon ionization of a hydrogenic state in the nonrelativistic dipole approximation. An application is made to the photoionization of the metastable $2S$ state of atomic hydrogen by optical radiation, for example, by the light from a ruby laser. The sum over intermediate states is carried out exactly by means of an implicit technique. The results are given for a range of wave-lengths from the threshold at 7290 down to 4556 \AA{}. At 6943 \AA{}, the total cross section per unit intensity is found to be 5.35\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}29}$ ${\mathrm{cm}}^{4}$ ${\mathrm{W}}^{\ensuremath{-}1}$. The lowest order damping corrections to the perturbation-theory results are worked out.
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