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It Is “Thiazolidene-2-imine” and Not Imidazole-2-thione as the Reaction Product of 1-Benzoyl-3-phenylthiourea with Br<sub>2</sub>/Enolizable Ketone
65
Citations
14
References
2006
Year
DerivativesReaction ProductEngineeringHeterocyclicOrganic Chemistry“ Thiazolidene-2-imine ”Imidazole-2-thione DerivativesThiazolidene-2-imine DerivativesSynthetic ChemistryChemistryHeterocycle ChemistryPharmacologyDerivative (Chemistry)Enolizable KetonesEnantioselective SynthesisBiomolecular Engineering
[Structure: see text] The products obtained by the reaction of benzoyl-3-phenylthioureas with bromine and enolizable ketones in the presence of triethylamine are not imidazole-2-thione derivatives as reported (Org. Lett. 2003, 5, 1657-1659) rather they are thiazolidene-2-imine derivatives.
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