CrystEngComm · 2008 · 24 citations · 43 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMaterials ChemistryNanomaterialsCoordination ChemistryCoordination PolymersHybrid MaterialsInorganic MaterialsTransition Metal ChemistryTransition Metal ComplexesCoordination Polymer SynthesisLanthanide Coordination ChemistryLanthanide Coordination PolymersMetal-ligand Coordination PolymersMetal-organic Framework SynthesisMetal-organic FrameworksOrganic-inorganic Hybrid MaterialsThree-dimensional Coordination Polymers
Presented here are three interesting I1O3 lanthanide-transition metal coordination polymers [Ln2Cu(μ6–O)1/6(μ3–OH)2/3(μ3–OH)2(hpzc)2(H2O)2]·2H2O [Ln = Dy(1), Ho(2), Er(3); Hhpzc = 3-hydroxy-pyrazine-2-carboxylic acid], based on nano-sized Ln-O-Ln inorganic rods and in situ obtained 3-hydroxy-pyrazine-2-carboxylate which came from pyrazine-2,3-dicarboxylic acid (H2pzdc). It is the first time that nanorods are incorporated into metal–organic frameworks.
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Reticular synthesis and the design of new materials
Omar M. Yaghi, M. O’Keeffe, N.W. Ockwig et al. · Nature · 2003 · 9K citations
Natural Sciences, Materials Engineering, Materials Science +9