Interactions in Nanosilica‐Polyurethane Composites Evidenced by Plate‐Plate Rheology and DMTA

Virtudes Navarro‐Bañón, José Roberto Vega‐Baudrit, Patricia Vázquez, José Miguel Martín‐Martínez

Macromolecular Symposia · 2005 · 23 citations · 0 references

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Abstract

Abstract Fumed nanosilicas with different degree of silanization were used to obtain nanosilica‐polyurethane (TPU) composites to modify their rheological and mechanical properties. The higher the silanol content of the nanosilica, the higher the storage modulus and the thermal stability of the silica‐TPU composite. DMTA experiments confirmed that the TPU‐silica interactions increased by increasing the silanol content of the nanosilica.