Concepedia

The structure of C60Ph5Cl and C60Ph5H, formed via electrophilic aromatic substitution

Anthony G. Avent, Paul R. Birkett, Jonathan D. Crane, Adam D. Darwish, G. John Langley, Harold W. Kroto, Roger Taylor, David R. M. Walton

Journal of the Chemical Society Chemical Communications · 1994 · 69 citations · 3 references

DOI

Concepts

Abstract

Reaction of C60Cl6 with benzene/FeCl3yields C60Ph5Cl which is readily reduced to C60Ph5H, the main product of reacting C60 with Br2/FeCl3/benzene; both compounds have been characterised by NMR spectroscopy.

References

3

C <sub>60</sub> H <sub>2</sub> : Synthesis of the Simplest C <sub>60</sub> Hydrocarbon Derivative

Craig C. Henderson, Paul A. Cahill · Science · 1993 · 227 citations

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Chlorination and bromination of fullerenes. Nucleophilic methoxylation of polychlorofullerenes and their aluminum trichloride catalyzed Friedel-Crafts reaction with aromatics to polyarylfullerenes

George A. Olah, Imre Bucsi, Christian Lambert et al. · Journal of the American Chemical Society · 1991 · 206 citations

, , +8

Multiple, reversible chlorination of C60

Fred N. Tebbe, James Y. Becker, D. Bruce Chase et al. · Journal of the American Chemical Society · 1991 · 143 citations

, , +9