Organic Letters · 2011 · 100 citations · 32 references
Natural SciencesBiochemistryChemistryCarbohydrate ChemistryCatalysisGlycosidic Bond FormationGlycosylation PathwaysActivation Methods For GlycosylationAnomeric SelectivityChemical GlycosylationGlycosyl Acceptor SynthesisGlycosyl Donor ActivationGlycosyl Donor ProtectionGlycosyl Donor ReactivityGlycosyl Donor Synthesis
Acid-base catalyzed glycosyl donor and then glycosyl acceptor activation with phenylboron difluoride or diphenylboron fluoride permits hydrogen bond mediated intramolecular S(N)2-type glycosidation in generally high anomeric selectivity.
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Mechanism of a Chemical Glycosylation Reaction
David Crich · Accounts of Chemical Research · 2010 · 508 citations