Concepedia

MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area

Thomas Devic, Christian Serre, Nathalie Audebrand, Jérôme Marrot, Gérard Férey

Journal of the American Chemical Society · 2005 · 437 citations · 11 references

DOI

Concepts

Abstract

A lanthanide-based metal organic framework, formulated Tb(C27H15O6)(H2O).2C6H11OH, has been solvothermally synthesized using the extended rigid tritopic ligand 1,3,5-tribenzoate. Included free solvent could be removed upon heating, and the resulting material presents large 1-D micropores (free diameter = 10 A) and a high surface area (SLangmuir > 1000 m2.g-1).

References

11

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Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb<sub>2</sub>(ADB)<sub>3</sub>[(CH<sub>3</sub>)<sub>2</sub>SO]<sub>4</sub>·16[(CH<sub>3</sub>)<sub>2</sub>SO]<sup>1</sup>

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Daniel T. de Lill, N.S. Gunning, Christopher L. Cahill · Inorganic Chemistry · 2004 · 227 citations

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