Journal of the Chemical Society Chemical Communications · 1994 · 6.6K citations · 11 references
Natural SciencesChemistryMaterials ScienceNanomaterialsNanotechnologySurface ScienceInorganic NanoparticlesNanomaterials SynthesisNanoparticle CharacterizationNanoparticle SurfacesNanoparticle SynthesisSurface Functionalization Of NanomaterialsColloidal NanoparticlesGold Nanoparticle SynthesisGold NanostructuresGold Surface FunctionalizationNanoparticlesNoble Metal NanostructuresThiol FunctionalizationThiol-based Surface Chemistry
Using two-phase (water–toluene) reduction of AuCl4– by sodium borohydride in the presence of an alkanethiol, solutions of 1–3 nm gold particles bearing a surface coating of thiol have been prepared and characterised; this novel material can be handled as a simple chemical compound.
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Marc D. Porter, Thomas B. Bright, David L. Allara et al. · Journal of the American Chemical Society · 1987 · 3.1K citations